Srikrishna, A and Danieldoss, S (1997) Chiral synthons from carvone .24. Photochemical rearrangements of chiral bicyclo[2.2.2]oct-5-en-2-ones. In: Synthetic Communications, 27 (4). pp. 655-661.
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Abstract
Photochemical oxadi-pi-methane rearrangement (1,2-acyl shift) of the chiral bicyclo[2.2.2]oct-5-en-2-ones 2 and 3 furnishes the tricyclic ketones 5 and 6, whereas the 1,3-acyl shift generates the cyclobutanones 7 and 8 respectively.
| Item Type: | Journal Article |
|---|---|
| Publication: | Synthetic Communications |
| Publisher: | Taylor and Francis Group |
| Additional Information: | Copyright of this article belongs to Taylor and Francis Group. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 29 May 2009 09:30 |
| Last Modified: | 19 Sep 2010 05:24 |
| URI: | http://eprints.iisc.ac.in/id/eprint/18692 |
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