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Simple linear-chain cobalt phosphates

Choudhury, A and Natarajan, S and Rao, CNR (2000) Simple linear-chain cobalt phosphates. In: Journal of The Chemical Society- Dalton Transactions (15). pp. 2595-2598.

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Two simple one-dimensional cobalt phosphates containing linear chains of corner-shared 4-membered rings have been synthesized hydrothermally by the reaction between amine phosphates and cobalt(II) ions under non-aqueous conditions. The linear chains are held together by hydrogen bond interactions involving the hydrogens of the amine and the framework oxygens. The two cobalt phosphates reported are the first linear chain compounds discovered in the family of open-framework transition metal phosphates.

Item Type: Journal Article
Publication: Journal of The Chemical Society- Dalton Transactions
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 20 Nov 2009 08:27
Last Modified: 19 Sep 2010 05:02
URI: http://eprints.iisc.ac.in/id/eprint/18501

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