Dithiaheterocycle-annelated tetrathiafulvalene pi-donors: a structure-property correlation study

Suresh Kumar, EVK and Singh, Jai D and Singh, Harkesh B and Das, Kalyan and Yakhmic, Jatinder V and Butcher, Ray J (1998) Dithiaheterocycle-annelated tetrathiafulvalene pi-donors: a structure-property correlation study. In: The Journal of Chemical society Parkin Trnansactions 1 (11). pp. 1769-1778.

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Abstract

Single-crystal X-ray structures of BEDT-TTF analogues 3, 6, 7 and 7a along with the preparation of a range of new cation-radical salts derived from these x-electron donors are reported. Physical properties (i.e. colour, cyclic voltammetry data and solid-state conductivities of the derived cation-radical salts) of the donors are discussed in terms of their crystal and molecular structures. The synthesis of compound 7 has been re-investigated. An efficient synthesis of both isomers 7 and 7a along with the other related TTF derivatives is presented. The crystal structure of the precursor thione 10 is also described.

Item Type:	Journal Article
Publication:	The Journal of Chemical society Parkin Trnansactions 1
Publisher:	Royal Society Chemistry
Additional Information:	Copyright of this article belongs to Royal Society Chemistry.
Department/Centre:	Division of Biological Sciences > Molecular Biophysics Unit
Date Deposited:	18 May 2009 09:40
Last Modified:	19 Sep 2010 05:01
URI:	http://eprints.iisc.ac.in/id/eprint/18419

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