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\mathit{N},O-Bis-(ethoxycarbonyl)hydroxylamine: a convenient reagent for the Lossen transformation

Anil, Kumar R and Chandrasekhar, Sosale and Sridhar, Malayalam (2000) \mathit{N},O-Bis-(ethoxycarbonyl)hydroxylamine: a convenient reagent for the Lossen transformation. In: Tetrahedron Letters, 41 (27). pp. 5291-5293.

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The titled compound effects the Lessen rearrangement on aromatic carboxylic acids, via activation by DCC or formation of the acid chlorides, to furnish the corresponding amines in excellent yields, in an essentially 'one-pot' procedure.

Item Type: Journal Article
Publication: Tetrahedron Letters
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: amines; carbamates; ethoxycarbonyl; hydroxylamine; Lossen.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 03 Nov 2009 09:45
Last Modified: 21 Feb 2019 09:07
URI: http://eprints.iisc.ac.in/id/eprint/18076

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