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An intramolecular rhodium carbenoid C-H insertion approach to chiral isotwistanes. Synthesis of (-)-neopupukean-4,10-dione and (-)-neopupukean-10-one

Srikrishna, A and Gharpure, Santosh J (1998) An intramolecular rhodium carbenoid C-H insertion approach to chiral isotwistanes. Synthesis of (-)-neopupukean-4,10-dione and (-)-neopupukean-10-one. In: Chemical Communication (15). pp. 1589-1590.

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Abstract

The first synthesis of a chiral neopupukeanane starting, from (R)-carvone and employing a double Michael reaction and a regioselective intramolecular rhodium carbenoid C-H insertion reaction as key steps, is described.

Item Type: Journal Article
Publication: Chemical Communication
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 26 Aug 2009 18:06
Last Modified: 19 Sep 2010 04:59
URI: http://eprints.iisc.ac.in/id/eprint/18025

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