A short and efficient regioselective approach to the C-6 to C-19 segment of bifurcaranes and a formal total synthesis of ${\beta}$-microbiotene, microbiotol and cyclocuparanol

Srikrishna, Adusumilli and Nagamani, Anitha S (1999) A short and efficient regioselective approach to the C-6 to C-19 segment of bifurcaranes and a formal total synthesis of ${\beta}$-microbiotene, microbiotol and cyclocuparanol. In: Perkin Transactions 1 (23). pp. 3393-3394.

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Abstract

Employing an epoxide rearrangement based ring contraction reaction, a short and efficient regioselective approach to the C-6 to C-19 segment of the toluquinol substituted diterpenes bifurcaranes, and its extension to a formal total synthesis of the sesquiterpenes (+/-)-beta-microbiotene, (+/-)-microbiotol and (+/-)-cyclocuparanol are described.

Item Type:	Journal Article
Publication:	Perkin Transactions 1
Publisher:	The Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to The Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	10 Feb 2010 07:19
Last Modified:	19 Sep 2010 04:59
URI:	http://eprints.iisc.ac.in/id/eprint/18009

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