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An open-framework iron phosphate with large voids, exhibiting spin-crossover

Choudhury, Amitava and Natarajan, Srinivasan and Rao, CNR (1999) An open-framework iron phosphate with large voids, exhibiting spin-crossover. In: Chemical Communications (14). pp. 1305-1306.

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A novel iron phosphate, [(C4N3H16)(C4N3H15)](5+)-[Fe5F4(H2PO4)(HPO4)(3)(PO4)(3)](5-). H2O, consisting of a Fe-O/F-Fe network crosslinked by PO4 groups is shown to possess unusually large elliptical voids of 24 T atoms (T = Fe, P) and to exhibit a gradual low- to high-spin transformation.

Item Type: Journal Article
Publication: Chemical Communications
Publisher: Royal Soc Chemistry
Additional Information: Copyright of this article belongs to Royal Soc Chemistry.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 10 Feb 2010 07:23
Last Modified: 19 Sep 2010 04:59
URI: http://eprints.iisc.ac.in/id/eprint/17966

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