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A heptacoordinated mononuclear diphenylantimony carboxylate

Swamy, KC Kumara and Said, Musa A and Netaji, M (1999) A heptacoordinated mononuclear diphenylantimony carboxylate. In: Journal of Chemical Crystallography, 29 (10). pp. 1103-1106.

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The X-ray structure of a novel mononuclear heptacoordinated compound chlorodiphenylantimony(V) bis(2-methyl benzoate), SbPh2CI(OC2-2-Me-C6H4)(2) is described. Crystal data are: Monoclinic, P2(1)/c, a = 8.791(3), b = 21.687(3), c = 13.488(4) Angstrom, beta = 10278(2)degrees, and Z = 4. A distorted pentagonal bipyramidal geometry for antimony with both the carboxylates chelating is found in the solid state.

Item Type: Journal Article
Publication: Journal of Chemical Crystallography
Publisher: Springer
Additional Information: Copyright of this article belongs to Springer.
Keywords: Antimony(V);Mononuclear carboxylate;Heptacoordinated;structure.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 12 Aug 2009 04:56
Last Modified: 19 Sep 2010 04:58
URI: http://eprints.iisc.ac.in/id/eprint/17802

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