Muthusamy, S and Gunanathan, C and Nethaji, M (2004) Stereoselective epoxide generation with cyclic rhodium carbenoids: A new access to spiro-indolooxiranes. In: Synlett (4). pp. 639-642.
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Official URL: http://www.thieme-connect.de/DOI/DOI?10.1055/s-200...
Abstract
The reaction of cyclic diazoamides with aryl aldehydes catalyzed by rhodium(II) acetate leads to intermolecular stereoselective epoxide ring formation. A series of spiro-indolooxiranes has been synthesized following the described method in a facile manner. The use of aryl dialdehydes in the course of reaction of cyclic diazoamide resulted the formation of bis-spiro-indolooxiranes.
| Item Type: | Journal Article |
|---|---|
| Publication: | Synlett |
| Publisher: | Thieme Medical Publishers |
| Additional Information: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | carbenoids;diazo ketones;oxiranes;rhodium(II) acetate;spiro compounds. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 19 Dec 2008 18:08 |
| Last Modified: | 19 Dec 2008 18:08 |
| URI: | http://eprints.iisc.ac.in/id/eprint/17314 |
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