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Desymmetrisation of a meso-N-hydroxyimide via a chiral Lossen reaction

Chandrasekhar, Sosale and Sridhar, Malayalam (2000) Desymmetrisation of a meso-N-hydroxyimide via a chiral Lossen reaction. In: Tetrahedron:Asymmetry, 11 (17). pp. 3467-3469.

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N-[(1S)-10-Camphorsulphonyloxy]norborn-5-ene-endo-2,3 dicarboximide 2 underwent a Lossen type reaction with dicyclohexylmethylamine to furnish endo-2-methoxycarbonyl-endo-3-(methoxycarbonyl-amino)norborn-5-ene 3, in 84% yield and 33% e.e. (by NMR).

Item Type: Journal Article
Publication: Tetrahedron:Asymmetry
Publisher: Elsevier
Additional Information: Copyright of this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 24 Dec 2008 05:56
Last Modified: 19 Sep 2010 04:54
URI: http://eprints.iisc.ac.in/id/eprint/17014

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