Roy, Mithun and Bhowmick, Tuhin and Ramakumar, Suryanarayanarao and Nethaji, Munirathinam and Chakravarty, Akhil R (2008) Double-strand DNA cleavage from photodecarboxylation of (\mu-oxo)diiron(III) L-histidine complex in visible light. In: Dalton Transactions (27). pp. 3542-3545.
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Abstract
The oxo-bridged diiron(III) complex $[\{Fe(L-his)(dpq)\}_2(\mu -O)]^{2+}$ having L-histidine (L-his) and dipyrido[3,2-d:$2^{\prime},3^{\prime}$-f]quinoxaline (dpq) bound to Fe(III) exemplifies an ironbased model photonuclease that shows visible light-induced DNA double-strand cleavage in a photodecarboxylation pathway and models iron-bleomycin activity.
Item Type: | Journal Article |
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Publication: | Dalton Transactions |
Publisher: | Royal Society of Chemistry |
Additional Information: | Copyright of this article belongs to Royal Society of Chemistry. |
Department/Centre: | Division of Information Sciences (Doesn't exist now) > BioInformatics Centre Division of Chemical Sciences > Inorganic & Physical Chemistry Division of Physical & Mathematical Sciences > Physics |
Date Deposited: | 31 Oct 2008 09:33 |
Last Modified: | 19 Sep 2010 04:51 |
URI: | http://eprints.iisc.ac.in/id/eprint/16291 |
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