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Metal-hydrazine complexes as precursors to oxide materials

Patil, KC (1986) Metal-hydrazine complexes as precursors to oxide materials. In: Chemical Sciences, 96 (6). pp. 459-464.

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Metal-hydrazine complexes, $[M(N_2,H_4)_n]^{2+}$ (M = Mn, Fe, Co, Ni, Zn and Cd, n = 2 or 3) with different anions like sulphate, sulphlte, acetate, formate, oxalate, hydrazinocarboxylate, nitrate and perchlorate have been investigated as precursors to oxide materials. The thermal reactivity of these complexes changes dramatically with the anion, e.g. sulphate, sulphite, acetate and formate complexes - decompose; oxaiate and hydrazinocarboxylates -deflagerate and nitrate and perchlorate complexes-detonate. The defiagerating nature of the metal-hydrazine oxalates and hydrazinocarboxylates has been employed in the combustion synthesis of fine particle $ y- Fe_2O_3, Fe_3O_4$, ferrites and cobaltites at low temperature.

Item Type: Journal Article
Publication: Chemical Sciences
Publisher: Indian Academy of Sciences
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Keywords: Metal-hydrazine complexes;precursors to oxide materials.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 05 Aug 2008
Last Modified: 19 Sep 2010 04:48
URI: http://eprints.iisc.ac.in/id/eprint/15389

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