Tris(dithiocarboxylato)indium(III): Thermal studies and crystal structure of $[In(S_2Ctol)_3]$

Ghoshal, Shamik and Kushwah, Nisha P and Pal, Manoj K and Jain, Vimal K and Nethaji, Munirathinam (2008) Tris(dithiocarboxylato)indium(III): Thermal studies and crystal structure of $[In(S_2Ctol)_3]$. In: Journal of Chemical Sciences, 120 (3). pp. 305-308.

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Abstract

Tris(dithiocarboxylato)indium(III), $[In\{S_2CAr\}_3]$ (Ar = phenyl or p-tolyl) have been synthesized and characterized. The molecular structure of $[In(S_2Ctol)_3]$ established by single crystal X-ray diffraction revealed a distorted octahedral geometry with symmetrically chelating dithiocarboxylate groups. These complexes on thermolysis gave $\beta-In_2S_3$ which was characterized by XRD and EDX.

Item Type:	Journal Article
Publication:	Journal of Chemical Sciences
Publisher:	Indian Academy of Sciences
Additional Information:	Copyright of this article belongs to Indian Academy of Sciences.
Keywords:	Indium; dithiocarboxylate; crystal structure;β-In2S3.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	11 Jul 2008
Last Modified:	19 Sep 2010 04:47
URI:	http://eprints.iisc.ac.in/id/eprint/14927

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