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Synthesis Based on Cyclohexadienes. Part $9.^1$ Total Synthesis of ( \pm )-Seychellene

Rao, Subba GSR and Bhaskar, Vijaya K (1993) Synthesis Based on Cyclohexadienes. Part $9.^1$ Total Synthesis of ( \pm )-Seychellene. In: Perkin Transactions 1, 1993 (9). pp. 2813-2816.

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A new strategy for the total synthesis of ( \pm )-seychellene 1 is described. The key step is an intramolecular Michael addition involving a 6-exo cyclisation with a vinyl radical derived from the acetylenic compound 11, obtained from the bicyclo[2.2.2]octene adduct 5 to the tricyclic intermediates 14 and 15.

Item Type: Journal Article
Publication: Perkin Transactions 1
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 08 Jul 2008
Last Modified: 19 Sep 2010 04:47
URI: http://eprints.iisc.ac.in/id/eprint/14844

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