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Self-Assembly of Metallamacrocycles via a Rigid Phosphorus Donor Linker

Ghosh, Sushobhan and Mukherjee, Partha Sarathi (2007) Self-Assembly of Metallamacrocycles via a Rigid Phosphorus Donor Linker. In: Organometallics, 26 (14). pp. 3362-3367.

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The coordination-driven self-assembly of a series of discrete 2D metallomacrocycles from a rigid diphosphine donor linker and Pd/Pt-containing 90° acceptors is described. All these assemblies are characterized by multinuclear NMR and, in four cases, X-ray crystallography. The selective formation of a diphosphine bridged macrocycle, {[(en)Pd(\mu-trans-PPh_2CH=CHPPh_2)_2Pd(en)]^{4+}}, from a 1:1:1 mixture of {cis-Pd(en)(NO_3)_2}, trans-{Ph_2PCH=CHPPh_2}, and 1,2-bis(4-pyridyl)ethane is also established.

Item Type: Journal Article
Publication: Organometallics
Publisher: American Chemical Society
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 03 Jul 2008
Last Modified: 19 Sep 2010 04:46
URI: http://eprints.iisc.ac.in/id/eprint/14724

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