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Magnetic properties of calcium iron manganese oxide $Ca_2Fe_2-\timesMn\timesO5$

Ganguli, AK and Gopalakrishnan, J (1986) Magnetic properties of calcium iron manganese oxide $Ca_2Fe_2-\timesMn\timesO5$. In: Journal of Chemical Sciences, 97 ((5-6)). pp. 627-630.

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Abstract

Magnetic susceptibility was studied of $Ca_2Fe_2-\timesMn\timesO5$ members crystg. in 2 different structures, one having octahedral (O), tetrahedral (T) and square-pyramidal (SP) coordination of transition metal atoms (OTSP structure) and the other having octahedral and tetrahedral coordination (OT structure). Susceptibility behavior of the oxides with OTSP structure is different from that of the oxides with OT structure. $Ca_2Fe1.33Mn0.67O5$ with OTSP structure shows an antiferromagnetic ordering while the corresponding oxide with OT structure shows weak ferromagnetism.

Item Type: Journal Article
Publication: Journal of Chemical Sciences
Publisher: Indian Academy of Sciences
Additional Information: Copyright of this article belongs to Indian academy of sciences
Keywords: Magnetic properties;calcium;iron;manganese;oxide
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 27 Jun 2008
Last Modified: 19 Sep 2010 04:46
URI: http://eprints.iisc.ac.in/id/eprint/14437

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