Rao, Subba GSR and Vijaybhaskar, K and Srikrishna, A (1986) Regioselective synthesis of 1-methylbicyclo[2.2.2]octene derivatives. In: Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 25B (8). pp. 785-786.
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1-Methylbicyclo[2.2.2]octenecarboxylic acids are prepd. by the cycloaddn. of dienophiles to 1-methylcyclohexa-1,3-diene-3-carboxylic acid $(I, R = H, R1 = CO2H)$ and 1-methylcyclohexa-1,3-diene-2-carboxylic acid $(I, R = CO2H, R1 = H)$. The addn. is regiospecific with $I (R = H, R1 = CO_2H)$ while poor regioselectivity is obsd. with $I (R = CO2H, R1 = H)$. Me esters of I are less reactive.
| Item Type: | Journal Article |
|---|---|
| Publication: | Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry |
| Publisher: | National Institute of Science Communication and Information Resources,CSIR |
| Additional Information: | copyright to this article belongs to National Institute of Science Communication and Information Resources,CSIR. |
| Keywords: | Regioselective synthesis;methylbicyclo octene;octene derivatives |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 18 Jun 2008 |
| Last Modified: | 27 Aug 2008 13:28 |
| URI: | http://eprints.iisc.ac.in/id/eprint/14378 |
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