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Chiral and Achiral Malate Frameworks with Different Dimensionalities

Ghosh, Anupama and Rao, CNR (2008) Chiral and Achiral Malate Frameworks with Different Dimensionalities. In: Zeitschrift für anorganische und allgemeine Chemie, 634 (6-7). pp. 1115-1122.

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A hybrid chain compound of the formula ${[Sr(L- C_4H_4O_5)·3H_2O]·H_2O}$ (1) and a hybrid double layered compound of the formula ${[Pb(L- C_4H_4O_5)]}$ (2) both with chiral structures, have been prepared strarting with L- malic acid, and characterized by X-ray crystallography and other techniques. An achiral three-dimensional hybrid compound of the composition ${[Pb(D,L- C_4H_4O_5)·2H_2O]}$ (3) has been obtained starting with D, L- malic acid. A chiral coordination polymer of $Cu^{11}$ with the formula ${[Cu_3(L-C_4H_3O_5)_2·4H_2O]·2H_2O}$ (4) has also been characterized. The structures as well as the novel coordination modes exhibited by 1-4 are discussed.

Item Type: Journal Article
Publication: Zeitschrift für anorganische und allgemeine Chemie
Publisher: John Wiley & Sons
Additional Information: Copyright of this article belongs to the John Wiley & Sons.
Keywords: Malic acid;Hybrid compounds;Chirality;Strontium malate;Lead malate.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 23 Jun 2008
Last Modified: 19 Sep 2010 04:45
URI: http://eprints.iisc.ac.in/id/eprint/14343

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