Rao, KJ and Rao, BG and Damodaran, RV and Selvaraj, U (1986) Novel glasses with octahedral structural groups. In: 14th International Congress on Glass, 1986, Calcutta, pp. 182-189.
Full text not available from this repository. (Request a copy)Abstract
Pb oxyhalide and K and Pb phosphomolybdate glass systems were studied. The structures of these glasses consist of networks built of octahedra. X-ray diffraction, EXAFS, ESR, and optical spectroscopic studies were used to show that [PbO2X4], (X = F, Cl) units are present in PbO-PbX2 glasses. Presence of [MoO6] units in phosphomolybdate glasses was established by using IR, optical and ESR spectroscopic studies. The behavior of bulk modulus and Poisson's ratio of phosphomolybdate glasses is discussed in the light of the various structural groups present
| Item Type: | Conference Paper |
|---|---|
| Publisher: | Indian Ceramamic Society |
| Additional Information: | Online version of the paper is not available |
| Keywords: | octahedral structure;Novel glasses;structural groups |
| Department/Centre: | Division of Chemical Sciences > Solid State & Structural Chemistry Unit |
| Date Deposited: | 24 Jun 2008 |
| Last Modified: | 27 Aug 2008 13:27 |
| URI: | http://eprints.iisc.ac.in/id/eprint/14340 |
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