Many-Body Effects in Electrochemisorption Part I. Green Function-Superoperator Formalism

Mishra, AK and Rangarajan, SK (1987) Many-Body Effects in Electrochemisorption Part I. Green Function-Superoperator Formalism. In: Journal of Electroanalytical Chemistry, 229 (1-2). pp. 51-65.

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Abstract

The way in which experimental obsetvables such as the partial charge and binding energy are related to the Hamiltonian via Green’s functions is demonstrated (a) The superoperator approach and (b) an imrer projection are employed to define respectively (i) the space stipulating the nature of the correlations (excitations) included in analysis and (ii) the Green’s functions appropriate to the subsystems of interest. The resulting analysis accounts for the many-body effects in a hierarchical manner.

Item Type:	Journal Article
Publication:	Journal of Electroanalytical Chemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	23 Jun 2008
Last Modified:	19 Sep 2010 04:45
URI:	http://eprints.iisc.ac.in/id/eprint/14335

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