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NO reduction by H2 over $nano-Ce_{0.98}Pd_{0.02}O_{2-\delta}$

Roy, Sounak and Marimuthu, A and Hegde, MS and Madras, Giridhar (2008) NO reduction by H2 over $nano-Ce_{0.98}Pd_{0.02}O_{2-\delta}$. In: Catalysis Communications, 9 (1). pp. 101-105.

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Development of new catalysts for controlling nitrogen oxides $(NO_x)$ emissions is an important technical challenge as increasingly strict emission limits are being imposed. A new catalyst $Pd^{2+}$ substituted $CeO_2$ $(Ce_{0.98}Pd_{0.02}O_{2-\delta})$ was synthesized by solution combustion method. The material was characterized by XRD, TEM and XPS and used to investigate the reduction of NO by $H_2$. The catalyst shows 100 \% $N_2$ selectivity at low temperature and thus is superior to other catalysts reported in literature. A bifunctional reaction mechanism has been proposed to model the experimental data.

Item Type: Journal Article
Publication: Catalysis Communications
Publisher: Elsevier
Additional Information: Copyright of this article belongs to Elsevier.
Keywords: De-NOx reaction by H2;Pd2+doped CeO2;Reaction mechanism.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Division of Mechanical Sciences > Chemical Engineering
Date Deposited: 10 Jun 2008
Last Modified: 19 Sep 2010 04:45
URI: http://eprints.iisc.ac.in/id/eprint/14244

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