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A Regioselective Total Synthesis of the Fungal Sesquiterpene $(\pm)$-Lagopodin A

Srikrishna, A and Babu, Ramesh R and Ravikumar, PC (2007) A Regioselective Total Synthesis of the Fungal Sesquiterpene $(\pm)$-Lagopodin A. In: Synlett (4). pp. 655-657.

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Abstract

A highly regiocontrolled total synthesis of fungal sesquiterpene lagopodin A, employing a combination of Claisen rearrangement-intramolecular diazoketone cyclopropanation and a highly regioselective cyclopropane ring cleavage, is described.

Item Type: Journal Article
Publication: Synlett
Publisher: Thieme Medical Publishers, Inc.
Additional Information: Copyright of this article belongs to Thieme Medical Publishers, Inc.
Keywords: natural products;total synthesis;rearrangement;ring closure;ring cleavage
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 03 Jun 2008
Last Modified: 27 Aug 2008 13:25
URI: http://eprints.iisc.ac.in/id/eprint/14151

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