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$Li_xPb_{1-2x}^{II}M^{III}_xO (M = Al, Fe):$ A new solid solution series related to yellow PbO

Tripathy, Mamata and Mani, Rohini and Gopalakrishnan, J (2006) $Li_xPb_{1-2x}^{II}M^{III}_xO (M = Al, Fe):$ A new solid solution series related to yellow PbO. In: Materials Research Bulletin, 41 (12). pp. 2244-2250.

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New series of oxides, $Li_xPb_{1-2x}^{II}M^{III}_xO (M = Al, Fe):$ , for 0< x \leq 0.33 adopting the yellow PbO structure have been synthesized by solid state reaction of $Li_2CO_3, Pb(NO_3)_2$ and $Al_2O_3/FeC_2O_4·2H_2O$ in air at $650-680 ^o C$. Optical absorption spectra reveal systematic increase/decrease of electronic band gap Eg for the Al/Fe members as compared to the parent yellow PbO. Partial deintercalation of lithium occurs under oxidative conditions $(Br_2/CH_3CN)$ with both the series.

Item Type: Journal Article
Publication: Materials Research Bulletin
Publisher: Elsevier
Additional Information: Copyright of this article belongs to Elsevier.
Keywords: Oxides;Chemical synthesis;X-ray diffraction;Optical properties
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 21 May 2008
Last Modified: 19 Sep 2010 04:45
URI: http://eprints.iisc.ac.in/id/eprint/14020

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