Bhatt, Vivekananda M and Vishwanatha, Somayaji and Shashidhar, MS (1984) Aspects of tautomerism: part 14 - alcoholysis of A-ring substituted o-benzoylbenzoyl chlorides: evidence for solvent involvement in determining nature of transition state. In: Indian Journal of Chemistry, Sect. B: Organic Chemistry including Medicinal Chemistry, 23 (12). pp. 1219-1222.
Full text not available from this repository. (Request a copy)Abstract
Rates of alcoholysis of A-ring substituted o-benzoylbenzoyl chlorides I $(R=H, Me, Br, NO_2)$ with 10% methanol, 10% ethanol, 50% isopropanol, and 50% cyclohexanol in acetone medium have been measured. The Hammett p-values range from -2.2 to -0.76. These results have been interpreted as evidence for transition states which vary gradually in their degree of charge separation and have features of both $SN_1$ and $SN_2$ reactions.
| Item Type: | Journal Article |
|---|---|
| Publication: | Indian Journal of Chemistry, Sect. B: Organic Chemistry including Medicinal Chemistry |
| Publisher: | Council of Scientific & Industrial Research |
| Additional Information: | Copyright of this article belongs to Council of Scientific & Industrial Research. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 07 May 2008 |
| Last Modified: | 27 Aug 2008 13:21 |
| URI: | http://eprints.iisc.ac.in/id/eprint/13841 |
Actions (login required)
 |
View Item |
