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Terpenoids. Part LXXX. Synthesis of 4-isopropyl-1,6-dimethyl-5,8-naphthoquinone (cadalenequinone)

Reddy, Kesavulu N and Rao, Krishna GS (1987) Terpenoids. Part LXXX. Synthesis of 4-isopropyl-1,6-dimethyl-5,8-naphthoquinone (cadalenequinone). In: Indian Journal of Chemistry, Sect. B: Organic Chemistry including Medicinal Chemistry, 26 (10). pp. 920-922.

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Abstract

Cadalenequinone (I), a naturally occurring cadalenic sesquiterpene naphthoquinone was prepared by 2 routes, starting from the tetralones II (R = Me, H) respectively. The first route gave I in an overall poor yield. The second route affords I in good yield, and also, in addition, 2 biogenetically interesting hydroxycadalenes III (R = CHO, Me).

Item Type: Journal Article
Publication: Indian Journal of Chemistry, Sect. B: Organic Chemistry including Medicinal Chemistry
Publisher: Council of Scientific & Industrial Research
Additional Information: Copyright of this article belongs to Council of Scientific & Industrial Research.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 18 Apr 2008
Last Modified: 22 Oct 2010 05:08
URI: http://eprints.iisc.ac.in/id/eprint/13757

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