Sreenivasulu, M and Rao, Krishna GS (1987) Vilsmeier-Haack reaction on some 3-buten-2-ols. In: Indian Journal of Chemistry, Sect. B: Organic Chemistry including Medicinal Chemistry, 26 (12). pp. 1187-1188.
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Vilsmeier-Haack reaction of $R_7R_8C:C(R_9)C(OH)(R_{10})CHR_{11}R_{12} (R_7, R_9, R_{10}, R_{12} = H, Me$; $R_8 = Me, Et, Pr, H$; $R_{11} = H, Me, Et)$ gave 6-26% benzenes I $(R_1 = CHO$; $R_2, R_4, R_6 = H, Me$; $R_3 = Me, CHO$; $R_5 = H, Me, Et, CHO)$. The presence of at least 5 appropriate participating C atoms on the butenol backbone was essential for formylative benzocyclization to occur.
Item Type: | Journal Article |
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Publication: | Indian Journal of Chemistry, Sect. B: Organic Chemistry including Medicinal Chemistry |
Publisher: | Council of Scientific & Industrial Research |
Additional Information: | Copyright of this article belongs to Council of Scientific & Industrial Research |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 17 Apr 2008 |
Last Modified: | 27 Aug 2008 13:20 |
URI: | http://eprints.iisc.ac.in/id/eprint/13755 |
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