Correlation Between a Structural Parameter and the Carboxyl $^{13}C$ Chemical Shielding Tensors in Compounds Containing Carboxylic Carbon as a Functional Group

Jagannathan, NR (1987) Correlation Between a Structural Parameter and the Carboxyl $^{13}C$ Chemical Shielding Tensors in Compounds Containing Carboxylic Carbon as a Functional Group. In: Chemical Physics Letters, 140 (6). pp. 548-552.

PDF correlation_13C.pdf Restricted to Registered users only Download (452kB) | Request a copy

Abstract

The influence of local molecular geometry on the carboxyl $^{13}C$ chemical shielding tensors in some organic molecules is investigated. The $\sigma_{22}$ component of the tensor shows a linear variation as a function of the OCO bond angle around the carboxyl carbon. The significance of the symmetry factors calculated for these compounds is discussed.

Item Type:	Journal Article
Publication:	Chemical Physics Letters
Publisher:	Elsevier Science B.V.
Additional Information:	Copyright of this article belongs to Elsevier Science B.V.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	01 Apr 2008
Last Modified:	19 Sep 2010 04:44
URI:	http://eprints.iisc.ac.in/id/eprint/13623

Actions (login required)

View Item