Solid-state Photochemistry of Nitro Compounds: Structure-Reactivity Correlations

Padmanabhan, Kaillathe and Dopp, Dietrich and Venkatesan, Kailasam and Ramamurthy, Vaidyanathan (1986) Solid-state Photochemistry of Nitro Compounds: Structure-Reactivity Correlations. In: Journal of the Chemical Society, Perkin Transactions 2 (24). 897 -906.

Preview

PDF solid.pdf Download (1MB)

Abstract

The molecu lar structures of 1 -t - butyl- 3,5-dimethyl-2,4,6- trinitrobenzene, 1 - t - butyl-3,4,5- trimethyl - 2'6 -dinitrobenzene, and 1 -t-butyl-4-acetyl-3,5-dimethyl-,6-dinitrobenzene have been determined by single-crystal X-ray analyses with a view to establishing a structure-reactivity relationship in the photochemical intramolecular hydrogen-abstraction process in the solid state. The reactivity of these aromatic nitro compounds in the solid state has been rationalized in terms of relevant intramolecular geometrical parameters as well as intermolecular packing considerations.

Item Type:	Journal Article
Publication:	Journal of the Chemical Society, Perkin Transactions 2
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	01 Apr 2008
Last Modified:	19 Sep 2010 04:44
URI:	http://eprints.iisc.ac.in/id/eprint/13537

Actions (login required)

View Item