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A novel anion induced cope rearrangement

Raghavan, S and Subba Rao, GSR (1992) A novel anion induced cope rearrangement. In: Tetrahedron Letters, 33 (1). pp. 119-120.

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1-Hydroxy-3-methoxy-4-(3-methylbut-2-enyl)xanthen-9-one undergoes an unusual Cope rearrangement in the presence of a base. A mechanism involving a p-dienone intermediate for this transformation is proposed.

Item Type: Journal Article
Publication: Tetrahedron Letters
Publisher: Elsevier Science Ltd.
Additional Information: Copyright of this article belongs to Elsevier Science Ltd.
Keywords: Cope Rearrangement;Xanthone
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 26 Mar 2008
Last Modified: 19 Sep 2010 04:43
URI: http://eprints.iisc.ac.in/id/eprint/13493

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