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One-Pot Benzoannulation of Homoallyl Alcohols: Vilsmeier Reaction Route to Biphenyls

Rao, Suresh CM and Rao, Krishna GS (1987) One-Pot Benzoannulation of Homoallyl Alcohols: Vilsmeier Reaction Route to Biphenyls. In: Synthesis (3). pp. 231-233.

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Abstract

The Vilsmeier reaction of 4-aryl-1-penten-4-ols and of 1-allyl-1-hydroxytetralins (prepared from the appropriate ketones by Grignard reaction) provides a one-pot general route for the preparation of biphenyls and 9,10-dihydrophenanthrenes, respectively. From suitably substituted starting materials, biphenyl-4-carboxaldehydes and dihydrophenanthrene-10-carboxaldehydes can be isolated in addition.

Item Type: Journal Article
Publication: Synthesis
Publisher: Thieme Chemistry
Additional Information: Copyright belongs to Thieme Chemistry
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 25 Mar 2008
Last Modified: 27 Aug 2008 13:16
URI: http://eprints.iisc.ac.in/id/eprint/13463

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