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Preparation and characterization of adducts of silicon tetrafluoride with thiazoles

Suresh, Bettadapura S and Padma, Doddaballapur K (1985) Preparation and characterization of adducts of silicon tetrafluoride with thiazoles. In: Journal of Fluorine Chemistry, 28 (2). pp. 207-218.

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Stable solid adducts of silicon tetrafluoride with the following thiazoles have been prepared: 2-aminothiazole, 2-amino-5-methylthiazole, 2-amino-6-methylbenzothiazole, 2-amino-7-nitrobenzothiazole and 2,4-dimethylthiazole. These adducts have been charactertsed by chemical and infrared spectral analysis. In all the cases except that of 2,4-dimethylthiazole ($SiF-4·2L$) the composition is 1:1. Both exocyclic and endocyclic nitrogen atoms are the coordinating centres in all the four cases while only endocyclic participates in coordination in the case of 2,4-dimethylthiazole. No indication has been found for the involvement of sulphur in coordination. Probable structures of these adducts have been proposed in which silicon is hexacoordinate

Item Type: Journal Article
Publication: Journal of Fluorine Chemistry
Publisher: Elsevier B.V
Additional Information: Copywright belongs to Elsevier Sequoia/Printed in The Netherlands
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 19 Mar 2008
Last Modified: 19 Sep 2010 04:43
URI: http://eprints.iisc.ac.in/id/eprint/13427

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