Preparation, characterization and thermal analysis of metal hydrazinocarboxylate derivatives

Ravindranathan, P and Patil, KC (1985) Preparation, characterization and thermal analysis of metal hydrazinocarboxylate derivatives. In: Proceedings of the Indian Academy of Sciences - Chemical Sciences, 95 (4). pp. 345-356.

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Abstract

The reaction of hydrazinocarboxylic acid, $N_2H_3COOH$, with metal ions in the presence of hydrazine hydrate yields metal hydrazinocarboxylate derivaties like: $M(N_2H_3COO)_2 \cdot nH_2O$, M = Mg, Ca and Mn; $M(N_2H_3COO)_2(N_2H_4)_2$, M = Mn, Fe, Co, Ni and Zn; $N_2H_5M(N_2H_3C00)_3 \cdot H_2O$, M = Fe, Co, Ni, Zn; and $N_2H_5Mg(N_2H_3COO)_3$. Reaction conditions to obtain a desired product have been standardised and a probable reaction mechanism for the formation of different products proposed. Thermal analysis of the compounds has been investigated using simultaneous TG-DTG-DTA. Metal hydrazino-carboxylate derivatives decompose in air at low temperatures to the respective metal oxides.

Item Type:	Journal Article
Publication:	Proceedings of the Indian Academy of Sciences - Chemical Sciences
Publisher:	Indian Academy of Sciences
Additional Information:	Copyright of this article belongs to Indian Academy of Sciences. The journal is presently known as the Journal of Chemical Sciences.
Keywords:	Metal hydrazinocarboxylates;infrared spectra;thermal analysis
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	18 Mar 2008
Last Modified:	19 Sep 2010 04:43
URI:	http://eprints.iisc.ac.in/id/eprint/13391

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