Swamy, Kumara KC and Ramabrahmam, P and Krishnamurthy, SS (1985) Studies of Phosphazenes: Part $27^1$. Synthesis of (Triphenylphosphazenyl)Pentachloro and Pentafluoro-Cyclotriphosphazenes. In: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 15 (8). pp. 1023-1035.
Full text not available from this repository. (Request a copy)Abstract
The triphenylphosphazenyl cyclophosphazene, $N_3P_3(N=PPh_3)Cl_5$ (1) has been prepared by two new methods using Appel and Staudinger reactions. The effect of solvent on the synthesis of 1 from the reaction of gem-$N_3P_3(NH_2)_2Cl_4$ with $Ph_3PCl_2$ (Kirsanov method) has been investigated. The fluoro compound, $N_3P_3(N=PPh3)F_5$(2), is obtained readily in good yields (85%) by the treatment of 1 with KF in methyl cyanide.
| Item Type: | Journal Article |
|---|---|
| Publication: | Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry |
| Publisher: | Taylor & Francis |
| Additional Information: | Copyright of this article belongs to Taylor & Francis. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 19 Mar 2008 |
| Last Modified: | 27 Aug 2008 13:16 |
| URI: | http://eprints.iisc.ac.in/id/eprint/13390 |
Actions (login required)
 |
View Item |
