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$^{13}C and ^1H$ NMR study of N-5'-methylsalicylideneanilines

Kishore, K and Sathyanarayana, DN and Bhanu, VA (1987) $^{13}C and ^1H$ NMR study of N-5'-methylsalicylideneanilines. In: Magnetic Resonance in Chemistry, 25 . pp. 471-473.

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The $^{13}C and ^1H$ NMR spectra of six N-5'-methylsalicylideneanilines have been studied. Correlations of the chem. shifts of C-\alpha (azomethine carbon) and C-4' with the \sigma, F, R, \sigma 1 and \sigmaR0 parameters have been examd. for N-5'-methylsalicylideneanilines, and also for N-benzylideneanilines and N-salicylideneanilines. The results suggest that the first compds. have a nearly planar conformation whereas the second and third type of derivs. have a twisted conformation.

Item Type: Journal Article
Publication: Magnetic Resonance in Chemistry
Publisher: John Wiley & Sons Ltd.
Additional Information: Copyright belongs to John Wiley and Sons Ltd.
Keywords: 13C and 1H NMR;N-5-methylsalicylideneanilines;F and R Conformation
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 06 Mar 2008
Last Modified: 19 Sep 2010 04:43
URI: http://eprints.iisc.ac.in/id/eprint/13204

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