Kinetics of electrode reactions occurring on porous iron electrodes in alkaline media

Vijayamohanan, K and Shukla, AK and Sathyanarayana, S (1990) Kinetics of electrode reactions occurring on porous iron electrodes in alkaline media. In: Journal of Electroanalytical Chemistry, 295 (1-2). pp. 59-70.

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Abstract

The kinetics of iron and hydrogen electrode reactions occurring on porous alkaline iron electrodes have been studied with the help of steady state and transient galvanostatic polarisation. Galvanostatic transients of porous iron electrodes in the linear polarisation regime have been analysed quantitatively, accounting for the charge-transfer and ohmic components of iron electrode reactions as well as the charge-transfer component of the hydrogen evolution reaction. These data, as also the volume of hydrogen evolved during these experiments, substantiate the catalytic effects of ferrous sulphide additives.

Item Type:	Journal Article
Publication:	Journal of Electroanalytical Chemistry
Publisher:	Eisevier Sequoia S.A.
Additional Information:	copyright of this article belongs to Eisevier Sequoia S.A.
Keywords:	electrode reactions
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	06 Feb 2008
Last Modified:	19 Sep 2010 04:41
URI:	http://eprints.iisc.ac.in/id/eprint/12658

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