Srikrishna, A and Hemamalini, P (1990) Radical Cyclization Strategies to Bridged Systems. Synthesis of Bicyclo[3.2.1]octan-3-ones from (S)-Carvone. In: Journal of Organic Chemistry, 55 (16). pp. 4883-4887.
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Abstract
Radical cyclization of the bromo enones I (R = H, R1R2 = O, R3 = Me, Et, H, Ac, CH2Ph), obtained by regiospecific bromoetherification at the electron-rich double bond of (S)-carvone, gave regio- and stereospecificially bicyclo[3.2.1]octan-3-ones II (R = H, R1R2 = O; R3 as above). Analogously, radical cyclizations of I (R = R1 = H, R2 = OH) gave II (R = R1 = H, R2 = OH) and I (R = Me, R1R2 = O) gave II (R = Me, R1R2 = O).
Item Type: | Journal Article |
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Publication: | Journal of Organic Chemistry |
Publisher: | ACS |
Additional Information: | Copyright of this article belongs to ACS publications |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 20 Dec 2007 |
Last Modified: | 19 Sep 2010 04:41 |
URI: | http://eprints.iisc.ac.in/id/eprint/12553 |
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