Total syntheses of (\pm)-\alpha-acorenol, \beta-acorenol, \alpha-epi-acorenol and \beta-epi-acorenol via an Ireland ester Claisen rearrangement and RCM reaction sequence

Srikrishna, A and Babu, Ramesh R (2007) Total syntheses of (\pm)-\alpha-acorenol, \beta-acorenol, \alpha-epi-acorenol and \beta-epi-acorenol via an Ireland ester Claisen rearrangement and RCM reaction sequence. In: Tetrahedron Letters, 48 (39). pp. 6916-6919.

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Abstract

Total syntheses of (\pm)-\alpha- and \beta-acorenols and (\pm)-\alpha- and \beta-epi-acorenols, spiro[4.5]decane sesquiterpenes, isolated from the western Australian sandalwood oil, have been accomplished employing a combination of Ireland ester Claisen rearrangement and RCM reactions for an efficient construction of the spiro[4.5]decane present in acoranes.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsevier
Additional Information:	Copyright of this article belongs to Elsevier.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	29 Oct 2007
Last Modified:	19 Sep 2010 04:41
URI:	http://eprints.iisc.ac.in/id/eprint/12398

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