The bicyclo[2.1.1]hexan-2-one system: a new probe for the experimental and computational study of electronic effects in pi-facial selectivity in nucleophilic additions

Mehta, Goverdhan and Singh, Robindro S and Gagliardini, Vanessa and Priyakumar, Deva U and Sastry, Narahari G (2001) The bicyclo[2.1.1]hexan-2-one system: a new probe for the experimental and computational study of electronic effects in pi-facial selectivity in nucleophilic additions. In: Tetrahedron Letters, 42 (48). pp. 8527-8530.

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Abstract

The remotely substituted 5-exo-bicyclo[2.1.1]hexan-2-one system is introduced as a new probe to study long range electronic effects on pi-face selectivity during hydride reduction and a systematic computational study demonstrates good predictability at the semi-empirical level.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsevier Science
Additional Information:	Copyright for this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	05 Aug 2004
Last Modified:	19 Sep 2010 04:14
URI:	http://eprints.iisc.ac.in/id/eprint/1234

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