An enantiospecific approach to (+)-thaps-8(11)-en-3-ol

Srikrishna, A and Anebouselvy, K (2002) An enantiospecific approach to (+)-thaps-8(11)-en-3-ol. In: Tetrahedron Letters, 43 (15). pp. 2769-2771.

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Abstract

An enantiospecific synthesis of a thapsane containing an oxygen substituent at the C-3 position is accomplished starting from (R)-carvone. A Claisen rearrangement and an intramolecular diazoketone cyclopropanation reaction were employed for the stereo- and regiospecific generation of the three contiguous quaternary carbon atoms present in the thapsanes.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsevier Science Ltd.
Additional Information:	Copyright of this article belongs to Elsevier Science Ltd.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	03 Oct 2007
Last Modified:	19 Sep 2010 04:39
URI:	http://eprints.iisc.ac.in/id/eprint/12006

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