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Thermodynamics of Binary Systems using Interaction Parameters

Hajra, JP and Mazumdar, B (1991) Thermodynamics of Binary Systems using Interaction Parameters. In: Metallurgical and Materials Transactions B, 22 (5). pp. 593-605.

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A four-parameter equation for determining the excess integral property of a binary system is deduced based on the Maclaurin infinite series. The series is expressed separately in the neighborhood of each of the pure components of the system. The components are subjected to appropriate boundary conditions at the various stages of the treatment. The present form of the function is found to be capable of interpreting thermodynamic properties of several relatively weakly interacting binary systems based on the present equation. The infinite dilution parameters compare favorably with the values reported in the literature.

Item Type: Journal Article
Publication: Metallurgical and Materials Transactions B
Publisher: Springer Boston
Additional Information: Copyright of this article belongs to Springer Boston.
Department/Centre: Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Date Deposited: 25 Sep 2007
Last Modified: 19 Sep 2010 04:39
URI: http://eprints.iisc.ac.in/id/eprint/11886

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