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Self-assembly of metal–organic hybrid nanoscopic rectangles

Ghosh, Sushobhan and Mukherjee, Partha Sarathi (2007) Self-assembly of metal–organic hybrid nanoscopic rectangles. In: Dalton Transactions (24). pp. 2542-2546.

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The combination of an amide containing a linear ligand (L1) and an organometallic molecular “clip” (clip-1) leads to the self-assembly of a $Pt_4$ nanoscopic framework representing the first example of a Pt-based molecular rectangle (rectangle-1) incorporating amide functionality. A complementary approach was also followed to prepare a Pd(II)-based molecular rectangle (rectangle-2) by reaction of a donor organic rigid clip (clip-2) and trans-$(PEt_3)_2Pd(OTf)_2$ as the linear metal acceptor (L2). The Pd(II)-rectangle was characterised by multinuclear NMR and ESI-mass spectroscopy.

Item Type: Journal Article
Publication: Dalton Transactions
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 11 Sep 2007
Last Modified: 19 Sep 2010 04:39
URI: http://eprints.iisc.ac.in/id/eprint/11801

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