Pradeep, T and Hegde, MS and Balakrishna, MS and Krishnamurthy, SS (1990) Electronic structures of $RN(PX_2)_2$ $(R=CH_3 or C_6H_5; X=Cl, OCH_3 or OC_6H_5)$ ligands: an ultraviolet photoelectron spectroscopic study. In: Journal of Electron Spectroscopy and Related Phenomena, 53 (3). pp. 119-127.
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Abstract
Vapour phase HeI photoelectron spectra of the diphosphazane ligands $RN(PX_2)_2$ $(R=CH_3 or C_6H_5, X=Cl, OCH_3 or OC_6H_5)$ are presented along with the assignments of bands on the basis of molecular orbital calculations. The spectra are in accordance with the structural studies which indicate multiple bonding in the $P-N-P$ segment. The phosphorus lone pair ionization energy appears to follow the a donor ability of the ligands.
Item Type: | Journal Article |
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Publication: | Journal of Electron Spectroscopy and Related Phenomena |
Publisher: | Elsevier Science |
Additional Information: | Copyright of this article belongs to Elsevier Science. |
Department/Centre: | Division of Chemical Sciences > Solid State & Structural Chemistry Unit Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 02 Jul 2007 |
Last Modified: | 18 Jan 2012 07:02 |
URI: | http://eprints.iisc.ac.in/id/eprint/11342 |
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