Varun, Begur Vasanthkumar and Gadde, Karthik and Prabhu, Kandikere Ramaiah (2015) Sulfenyiation of beta-Diketones Using C-H Functionalization Strategy. In: ORGANIC LETTERS, 17 (12). pp. 2944-2947.
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Official URL: http://dx.doi.org/10.1021/acs.orglett.5b01221
Abstract
Sulfenylation of beta-diketones is challenging as beta-diketones undergo deacylation after sulfenylation in the reaction medium. The sulfenylation of beta-diketones without deacylation under metal-free conditions at ambient temperature via a cross dehydrogenative coupling (CDC) strategy is reported. The resultant products can be further manipulated to form alpha,alpha-disubstituted beta-diketones and pyrazoles.
| Item Type: | Journal Article |
|---|---|
| Publication: | ORGANIC LETTERS |
| Publisher: | AMER CHEMICAL SOC |
| Additional Information: | Copy right for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 31 Jul 2015 13:06 |
| Last Modified: | 31 Jul 2015 13:06 |
| URI: | http://eprints.iisc.ac.in/id/eprint/51953 |
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