Dhar, Joydeep and Swathi, K and Karothu, Durga Prasad and Narayan, KS and Patil, Satish (2015) Modulation of Electronic and Self-Assembly Properties of a Donor-Acceptor-Donor-Based Molecular Materials via Atomistic Approach. In: ACS APPLIED MATERIALS & INTERFACES, 7 (1). pp. 670-681.
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Abstract
The performance of molecular materials in optoelectronic devices critically depends upon their electronic properties and solid-state structure. In this report, we have synthesized sulfur and selenium based (T4BT and T4BSe) donor-acceptor-donor (D-A-D) organic derivatives in order to understand the structure-property correlation in organic semiconductors by selectively tuning the chalcogen atom. The photophysical properties exhibit a significant alteration upon varying a single atom in the molecular structure. A joint theoretical and experimental investigation suggests that replacing sulfur with selenium significantly reduces the band gap and molar absorption coefficient because of lower electronegativity and ionization potential of selenium. Single-crystal X-ray diffraction analysis showed differences in their solid-state packing and intermolecular interactions. Subsequently, difference in the solid-state packing results variation in self-assembly. Micorstructural changes within these materials are correlated to their electrical resistance variation, investigated by conducting probe atomic force microscopy (CP-AFM) measurements. These results provide useful guidelines to understand the fundamental properties of D-A-D materials prepared by atomistic modulation.
Item Type: | Journal Article |
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Publication: | ACS APPLIED MATERIALS & INTERFACES |
Publisher: | AMER CHEMICAL SOC |
Additional Information: | Copyright for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
Keywords: | selenium; electronic property; self-assembly; microstructure; conductivity |
Department/Centre: | Division of Chemical Sciences > Solid State & Structural Chemistry Unit |
Date Deposited: | 16 Mar 2015 05:11 |
Last Modified: | 16 Mar 2015 05:11 |
URI: | http://eprints.iisc.ac.in/id/eprint/51048 |
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