ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

An Unusual Ring-Contraction/Rearrangement Sequence for Making Functionalized Di- and Triquinanes

Nagaraju, Chinta and Prasad, Kavirayani R (2014) An Unusual Ring-Contraction/Rearrangement Sequence for Making Functionalized Di- and Triquinanes. In: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 53 (41). pp. 10997-11000.

[img] PDF
ang_ahe_int_edi_53-41_10997_2014.pdf - Published Version
Restricted to Registered users only

Download (687kB) | Request a copy
Official URL: http://dx.doi.org/ 10.1002/anie.201407680

Abstract

A novel ring contraction/rearrangement sequence leading to functionalized 2,8-oxymethano-bridged di- and triquinane compounds is observed in the reaction of various substituted 1-methyl-4-isopropenyl-6-oxabicylo3.2.1]octan-8-ones with Lewis acids. The reaction is novel and is unprecedented for the synthesis of di- and triquinane frameworks.

Item Type: Journal Article
Publication: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Additional Information: Copy right for this article belongs to the WILEY-V C H VERLAG GMBH, BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 14 Dec 2014 10:48
Last Modified: 14 Dec 2014 10:48
URI: http://eprints.iisc.ac.in/id/eprint/50443

Actions (login required)

View Item View Item