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Stereoselective geminal difunctionalization of vinyl arenes mediated by the bromonium ion

Balaji, Pandur Venkatesan and Chandrasekaran, Srinivasan (2014) Stereoselective geminal difunctionalization of vinyl arenes mediated by the bromonium ion. In: CHEMICAL COMMUNICATIONS, 50 (1). pp. 70-72.

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Official URL: http://dx.doi.org/10.1039/c3cc46003g

Abstract

An anti-Markovnikov geminal oxyamination of styrenyl alkenes in an intermolecular fashion using the umpolung strategy mediated by the bromonium ion is reported. Isotope labeling studies confirm the migration of the phenyl group in the semipinacol rearrangement.

Item Type: Journal Article
Publication: CHEMICAL COMMUNICATIONS
Publisher: ROYAL SOC CHEMISTRY
Additional Information: copyright for this article belongs to ROYAL SOC CHEMISTRY,ENGLAND
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 16 Jan 2014 09:44
Last Modified: 16 Jan 2014 09:44
URI: http://eprints.iisc.ac.in/id/eprint/48042

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