Kasturi, TR and Arumugam, S (1996) Potassamide induced in situ alkylation of 5,6-dihydroisoquinoline with allyl bromide and Michael acceptors. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 35 (5). pp. 468-470.
Full text not available from this repository. (Request a copy)Abstract
Potassamide induced in situ alkylation of 4-cyano-3-methoxy-1-methyl-5, 6-dihydroisoquinoline (1a) with allyl bromide gives the 5-allyl- and 5,9-diallyl-5,6-dihydroisoquinolines (1c and 1d), isoquinoline derivative 2 and 4-allyl-1, 2, 3, 4-tetrahydroisoquinolin-3(2H)-one (3a). However, potassamide induced in situ alkylation of In with buten-2-one, mesityl oxide and acrylonitrile results in the formation of only 5-alkylated 5,6-dihydroisoquinoline derivatives 1e-g along with fully aromatised compound 2.
| Item Type: | Journal Article |
|---|---|
| Publication: | Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry |
| Publisher: | National Institute of Science Communication and Information Resources |
| Additional Information: | Copyright of this article belongs to National Institute of Science Communication and Information Resources. |
| Keywords: | alkylation;arylation;dealkylation;dearylation;C-acylation, olefination;isoquinoline derivatives |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 09 May 2011 10:45 |
| Last Modified: | 09 May 2011 10:45 |
| URI: | http://eprints.iisc.ac.in/id/eprint/37474 |
Actions (login required)
 |
View Item |
