Srikrishna, A and Satyanarayana, G (2006) Total synthesis of (+/-)-herbertenediol. In: Tetrahedron, 62 (12). pp. 2892-2900.
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Official URL: http://dx.doi.org/10.1016/j.tet.2006.01.021
Abstract
A formal total synthesis of the sesquiterpene (+/-)-herbertenediol and its dimers mastigophorenes A-D has been accomplished, starting from vanillin via 2,3-dimethoxy-5-methylbenzaldehyde. A combination of Claisen rearrangement and ring-closing metathesis reactions were employed for the generation of the two vicinal quaternary carbons on a cyclopentane ring.
| Item Type: | Journal Article |
|---|---|
| Publication: | Tetrahedron |
| Publisher: | Elsevier Science |
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Herbertanes; mastigophorenes; RCM reaction; Claisen rearrangement; vicinal quaternary carbon atoms. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 16 Sep 2010 05:24 |
| Last Modified: | 19 Sep 2010 06:15 |
| URI: | http://eprints.iisc.ac.in/id/eprint/31754 |
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