Srikrishna, A and Ravi, G (2008) A stereoselective total synthesis of (−)-seychellene. In: Tetrahedron Letters, 64 (11). pp. 2565-2571.
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Abstract
A stereoselective total synthesis of the tricyclic sesquiterpene (−)-seychellene, starting from (R)-carvone via (R)-3-methylcarvone has been accomplished, employing a combination of intermolecular Michael addition–intramolecular Michael addition sequence, a stereoselective hydrogenation, and an intramolecular alkylation reaction.
| Item Type: | Journal Article |
|---|---|
| Publication: | Tetrahedron Letters |
| Publisher: | Elsevier Science |
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Seychellene;Sesquiterpene synthesis;Intramolecular alkylation;Carvone;Double Michael reaction. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 08 Mar 2010 10:53 |
| Last Modified: | 19 Sep 2010 05:56 |
| URI: | http://eprints.iisc.ac.in/id/eprint/25936 |
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