Metal chelates in vinyl polymerization. II. Mechanism of initiation by Fe(DPM)3

Prabha, R and Nandi, US (1976) Metal chelates in vinyl polymerization. II. Mechanism of initiation by Fe(DPM)3. In: Journal of Polymer Science: Polymer Chemistry Edition, 15 (8). pp. 1983-1989.

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Abstract

The nature of the interaction between the unsaturated monomer and the chelate, Fe(DPM)3, is studied in detail. The interaction is found to occur only in solution. The stoichiometry of interaction and the equilibrium constant are evaluated. With the help of spectral evidence, attempts are made to point out the specific sites of interaction.

Item Type:	Journal Article
Publication:	Journal of Polymer Science: Polymer Chemistry Edition
Publisher:	Wiley Interscience
Additional Information:	Copyright for this article belongs to Wiley Interscience.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	20 Jan 2010 05:40
Last Modified:	19 Sep 2010 05:50
URI:	http://eprints.iisc.ac.in/id/eprint/24483

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